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ASTM-C1285:2008 Edition

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C1285-02(2008) Standard Test Methods for Determining Chemical Durability of Nuclear, Hazardous, and Mixed Waste Glasses and Multiphase Glass Ceramics: The Product Consistency Test (PCT)

Published By Publication Date Number of Pages
ASTM 2008 23
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ASTM C1285-02-Reapproved2008

Historical Standard: Standard Test Methods for Determining Chemical Durability of Nuclear, Hazardous, and Mixed Waste Glasses and Multiphase Glass Ceramics: The Product Consistency Test (PCT)

ASTM C1285

Scope

1.1 These product consistency test methods A and B evaluate the chemical durability of homogeneous glasses, phase separated glasses, devitrified glasses, glass ceramics, and/or multiphase glass ceramic waste forms hereafter collectively referred to as glass waste forms by measuring the concentrations of the chemical species released to a test solution.

1.1.1 Test Method A is a seven-day chemical durability test performed at 90 ± 2°C in a leachant of ASTM-Type I water. The test method is static and conducted in stainless steel vessels. Test Method A can specifically be used to evaluate whether the chemical durability and elemental release characteristics of nuclear, hazardous, and mixed glass waste forms have been consistently controlled during production. This test method is applicable to radioactive and simulated glass waste forms as defined above.

1.1.2 Test Method B is a durability test that allows testing at various test durations, test temperatures, mesh size, mass of sample, leachant volume, and leachant compositions. This test method is static and can be conducted in stainless steel or PFA TFE-fluorocarbon vessels, or both. Test Method B can specifically be used to evaluate the relative chemical durability characteristics of homogeneous glasses, phase separated glasses, devitrified glasses, glass ceramics, and/or multiphase glass ceramic waste forms. This test method is applicable to radioactive (nuclear) and mixed, hazardous, and simulated waste forms as defined above. Test Method B cannot be used as a consistency test for production of high level radioactive glass waste forms.

1.2 These test methods must be performed in accordance with all quality assurance requirements for acceptance of the data.

1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

Keywords

Glass waste forms; Homogeneous glass; Multiphase glass ceramic waste forms; Nuclear applications/materials; Nuclear scrap and waste materials; Nuclear waste glasses; Phase separation; Product consistency test (PCT); Chemical analysis–nuclear materials; Chemical durability; Devitrified glass; Durability; Elemental release; Glass ceramics

ICS Code

ICS Number Code 13.030.30 (Special wastes)

DOI: 10.1520/C1285-02R08

PDF Catalog

PDF Pages PDF Title
1 Scope
Referenced Documents
2 Terminology
3 Summary of Test Methods
Significance and Use
TABLE 1
FIG. 1
4 Apparatus
Standards
5 Reagents and Standards
Hazards
Choice of Test Vessel
6 Identification of Vessels and Vessel Cleaning History
Cleaning of New Stainless Steel Vessels for PCT Test Methods A and B
Cleaning of New TFE-fluorocarbon Gaskets for Stainless Steel Vessels for PCT Test Methods A and B
Cleaning of Used Stainless Steel Vessels for PCT Test Method A
7 Cleaning of Used Stainless Steel Vessels for PCT Test Method B
Cleaning of New PFA TFE-fluorocarbon Vessels for PCT Test Method B
8 Cleaning of Used PFA TFE-fluorocarbon Vessels for PCT Test Method B
Calibration
Sample Preparation for PCT Test Method A
10 Preparation of Reference Waste Form for PCT Test Method A
Procedure—PCT Test Method A
FIG. 2
12 Sample Preparation for PCT Test Method B
14 Preparation of Reference Waste Form for PCT Test Method B
Procedure—PCT Test Method B
15 Calculation
17 Report
Precision and Bias
19 X1. SAMPLE CALCULATION OF THE EXPOSED GLASS WASTE FORM SURFACE AREA
X1.1
FIG. 3
21 X2. MODEL PCT DATA SHEET
22 REFERENCES
ASTM-C1285
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