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ASTM-D3612:2002 Edition

$58.50

D3612-02e1 Standard Test Method for Analysis of Gases Dissolved in Electrical Insulating Oil by Gas Chromatography

Published By Publication Date Number of Pages
ASTM 2002 22
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ASTM D3612-02e1

Historical Standard: Standard Test Method for Analysis of Gases Dissolved in Electrical Insulating Oil by Gas Chromatography

ASTM D3612

Scope

1.1 This test method covers three procedures for extraction and measurement of gases dissolved in electrical insulating oil having a viscosity of 20 cSt (100 SUS) or less at 40°C (104°F), and the identification and determination of the individual component gases extracted. Other methods have been used to perform this analysis.

1.2 The individual component gases that may be identified and determined include:

1.3 WarningMercury has been designated by EPA and many state agencies as a hazardous material that can cause central nervous system, kidney, and liver damage. Mercury, or its vapor, may be hazardous to health and corrosive to materials. Caution should be taken when handling mercury and mercury-containing products. See the applicable product Material Safety Data Sheet (MSDS) for details and EPAs website (http://www.epa.gov/mercury/faq.htm) for additional information. Users should be aware that selling mercury or mercury-containing products, or both, in your state may be prohibited by state law.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific warning statements see 6.1.8, 30.2.2 and 30.3.1.

Keywords

capillary columns; combustible gases; dissolved gases; gases; headspace; insulating oil; oil; transformer oil; Dissolved gases; Electrical insulating oils; Gas chromatography (GC)–insulating materials/applications; Gas content

ICS Code

ICS Number Code 29.040.10 (Insulating oils)

DOI: 10.1520/D3612-02E01

PDF Catalog

PDF Pages PDF Title
1 Scope
Referenced Documents
Terminology
2 Summary of Test Method
Significance and Use
Apparatus
Sampling
3 FIG. 1
FIG. 2
4 Method A—Vacuum Extraction
Preparation of Apparatus
Procedure
FIG. 3
5 Apparatus
Reagent and Materials
6 Calibration
FIG. 4
7 Procedure
Calculation
Report
Precision and Bias
TABLE 1
8 Method B—Stripper Column Extraction
Apparatus
Reagent and Materials
9 FIG. 5
10 Calibration (Gases)
Efficiency Determination
Procedure for Direct Injection
Calculation
Report
Precision and Bias
11 TABLE 2
TABLE 3
12 FIG. 6
13 Method C—Headspace sampling
Apparatus
14 Chemicals
Procedure
FIG. 7
TABLE 4
TABLE 5
15 FIG. 8
16 Determination of Partition Coefficients
TABLE 6
17 Calculation
Report
Precision and Bias
Keywords
18 A1. PREPARATION OF SMALL QUANTITIES OF GAS-IN-OIL STANDARDS (Mandatory Information—Method B)
A1.1 Calibration Apparatus
A1.2 Procedure
TABLE 7
19 A2. PREPARATION OF LARGE QUANTITIES OF GAS-IN-OIL STANDARDS (Mandatory Information—Method B)
A2.1 Apparatus
A2.2 Materials
A2.3 Preparation of Apparatus
FIG. A2.1
FIG. A2.2
20 A2.4 Procedure
A2.5 Calculation
A2.6 Reliability
FIG. A2.3
21 X1. PRECISION AND BIAS OF GAS RATIOS USED IN FAULT DIAGNOSIS IN OIL-INSULATED ELECTRICAL EQUIPMENT
X1.1
FIG. X1.1
ASTM-D3612
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