This European Standard specifies requirements and test methods for the substances and materials used in chemical toys (sets) other than experimental sets. These substances and mixtures are:<\/p>\n
those classified as dangerous by the EC-legislation applying to dangerous substances and dangerous mixtures [5];<\/p>\n<\/li>\n
substances and mixtures which in excessive amounts could harm the health of the children using them and which are not classified as dangerous by the above mentioned legislation; and<\/p>\n<\/li>\n
any other chemical substance(s) and mixture(s) delivered with the chemical toy.<\/p>\n<\/li>\n<\/ul>\n
\nNOTE The terms \u201csubstance\u201d and \u201cmixture\u201d are defined in the REACH regulation No. (EC)1907\/2006 and in the CLP regulation (EC) No. 1272\/2008.<\/p>\n<\/blockquote>\n
Additionally, requirements are specified for markings, warnings, safety rules, contents list, instructions for use and first aid information.<\/p>\n
This Part of EN 71 applies to:<\/p>\n
\n
- \n
plaster of Paris (gypsum) moulding sets;<\/p>\n<\/li>\n
- \n
ceramic and vitreous enamelling materials supplied in miniature workshop sets;<\/p>\n<\/li>\n
- \n
oven-hardening plasticised PVC modelling clay sets;<\/p>\n<\/li>\n
- \n
plastic moulding sets;<\/p>\n<\/li>\n
- \n
embedding sets;<\/p>\n<\/li>\n
- \n
adhesives, paints, lacquers, varnishes, thinners and cleaning agents (solvents), supplied or recommended in model sets.<\/p>\n<\/li>\n<\/ul>\n
PDF Catalog<\/h4>\n
\n
\n PDF Pages<\/th>\n PDF Title<\/th>\n<\/tr>\n \n 4<\/td>\n Contents Page <\/td>\n<\/tr>\n \n 6<\/td>\n Foreword <\/td>\n<\/tr>\n \n 8<\/td>\n Introduction <\/td>\n<\/tr>\n \n 9<\/td>\n 1 Scope
2 Normative references
3 Terms and definitions <\/td>\n<\/tr>\n\n 11<\/td>\n 4 Plaster of Paris (gypsum) moulding sets
4.1 Marking
4.2 First aid information
4.3 Safety rules <\/td>\n<\/tr>\n\n 12<\/td>\n 5 Ceramic and vitreous enamelling materials supplied in miniature workshop sets
5.1 Chemical mixtures
5.2 Marking
5.3 First aid information <\/td>\n<\/tr>\n\n 13<\/td>\n 5.4 Safety rules
6 Oven-hardening plasticised PVC modelling clay sets
6.1 Chemical substances <\/td>\n<\/tr>\n\n 14<\/td>\n 6.2 Marking
6.3 First aid information
6.4 Safety rules
7 Plastic moulding sets
7.1 Polystyrene granules
7.1.1 Chemical substances <\/td>\n<\/tr>\n\n 15<\/td>\n 7.1.2 Marking
7.1.3 First aid information
7.1.4 Safety rules
7.2 Embedding sets
7.2.1 General
7.2.2 Packaging <\/td>\n<\/tr>\n\n 16<\/td>\n 7.2.3 Marking
7.2.4 First aid information
7.2.5 Safety rules
8 Adhesives, paints, lacquers, varnishes, thinners and cleaning agents (solvents) supplied or recommended in model sets
8.1 General
8.2 Adhesives
8.2.1 Water-based adhesives
8.2.1.1 General <\/td>\n<\/tr>\n\n 17<\/td>\n 8.2.1.2 Liquid adhesives for paper and wood <\/td>\n<\/tr>\n \n 18<\/td>\n 8.2.1.3 Adhesive sticks for paper <\/td>\n<\/tr>\n \n 19<\/td>\n 8.2.2 Solvent-based adhesives
8.2.2.1 General
8.2.2.2 Multi-purpose adhesives <\/td>\n<\/tr>\n\n 20<\/td>\n 8.2.2.3 Contact adhesives
8.2.2.4 Special adhesives <\/td>\n<\/tr>\n\n 22<\/td>\n 8.2.2.5 Packaging
8.2.2.6 Marking
8.2.2.7 First aid information
8.2.2.8 Safety rules
8.3 Water-based paints and lacquers
8.3.1 General <\/td>\n<\/tr>\n\n 23<\/td>\n 8.3.2 Packaging
8.3.3 Marking
8.3.4 First aid information <\/td>\n<\/tr>\n\n 24<\/td>\n 8.3.5 Safety rules
8.4 Solvent-based paints, lacquers, thinners and cleaning solvents
8.4.1 General <\/td>\n<\/tr>\n\n 25<\/td>\n 8.4.2 Packaging
8.4.3 Marking
8.4.4 First aid information <\/td>\n<\/tr>\n\n 26<\/td>\n 8.4.5 Safety rules
9 Marking
9.1 General
9.2 Marking of the primary packaging
9.2.1 General
9.2.2 Manufacturer\u2019s identification
9.2.3 Warning phrases
9.3 Marking of individual containers and any packagings <\/td>\n<\/tr>\n\n 27<\/td>\n 10 Instructions for use
10.1 General
10.2 Contents list
10.3 Advice for adult supervision <\/td>\n<\/tr>\n\n 28<\/td>\n 10.4 Safety rules
10.5 Instructions for carrying out the activities
10.6 Spills and disposal of chemicals <\/td>\n<\/tr>\n\n 29<\/td>\n 11 Test methods
11.1 General
11.2 Determination of elements in ceramic and vitreous enamelling materials
11.2.1 Principle
11.2.2 Standards and reagents
11.2.2.1 Standards
11.2.2.2 Reagents <\/td>\n<\/tr>\n\n 30<\/td>\n 11.2.3 Apparatus
11.2.4 Preparation of standard solutions
11.2.4.1 Multi-element standard solution I
11.2.4.2 Multi-element standard solution II
11.2.4.3 Multi-element standard solution III
11.2.5 Blank solution
11.2.6 Sampling <\/td>\n<\/tr>\n\n 31<\/td>\n 11.2.7 Sample preparation
11.2.8 Procedure
11.2.9 Evaluation of results
11.2.9.1 General <\/td>\n<\/tr>\n\n 33<\/td>\n 11.2.9.2 Calculation of the pigment contents in the enamel samples <\/td>\n<\/tr>\n \n 34<\/td>\n 11.2.10 Test report
11.3 Determination of plasticisers in oven-hardening polyvinyl chloride (PVC) modelling clay sets
11.3.1 Principle <\/td>\n<\/tr>\n\n 35<\/td>\n 11.3.2 Standards and reagents
11.3.2.1 Standards <\/td>\n<\/tr>\n\n 36<\/td>\n 11.3.2.2 Reagents
11.3.3 Apparatus <\/td>\n<\/tr>\n\n 39<\/td>\n 11.3.4 Preparation of standard solutions
11.3.4.1 Stock solutions <\/td>\n<\/tr>\n\n 40<\/td>\n 11.3.4.2 Calibration solutions <\/td>\n<\/tr>\n \n 41<\/td>\n 11.3.4.3 Stability of standard solutions
11.3.5 Sampling
11.3.6 Sample preparation
11.3.7 Procedure
11.3.7.1 Extraction of phthalic acid esters, citric acid esters and alkylsulfonic acid esters <\/td>\n<\/tr>\n\n 42<\/td>\n 11.3.7.2 Extraction of adipic acid polyesters
11.3.7.3 Evaporation of the solvent and weighing
11.3.7.4 Blank determination
11.3.7.5 GC-MSD determination of phthalic acid esters, citric acid esters and alkylsulfonic acid esters <\/td>\n<\/tr>\n\n 43<\/td>\n 11.3.7.6 ATR-FT-IR identification of adipic acid polyesters
11.3.8 Evaluation of results
11.3.8.1 Calculation of solvent-extractable content containing plasticisers <\/td>\n<\/tr>\n\n 44<\/td>\n 11.3.8.2 Calculation and identification of plasticiser content by GC-MS analysis <\/td>\n<\/tr>\n \n 45<\/td>\n 11.3.9 Test report <\/td>\n<\/tr>\n \n 46<\/td>\n 11.4 Determination of the emission of benzene, toluene and xylenes from oven-hardening plasticised PVC modelling clay sets and plastic moulding sets
11.4.1 Principle
11.4.2 Standards and reagents
Chemical
CAS No.
Toluene
108-88-3
Benzene
71-43-2
o-Xylene
95-47-6
m-Xylene
108-38-3
p-Xylene
106-42-3
Chemical
CAS No.
Methanol
67-56-1
11.4.3 Apparatus <\/td>\n<\/tr>\n\n 48<\/td>\n 11.4.4 Preparation of standard solutions
11.4.5 Sampling
11.4.6 Sample preparation
11.4.7 Procedure <\/td>\n<\/tr>\n\n 49<\/td>\n 11.4.8 Evaluation of results
11.4.9 Test report
11.4.10 Critical control points
11.5 Determination of styrene content in polystyrene granules
11.5.1 Principle <\/td>\n<\/tr>\n\n 50<\/td>\n 11.5.2 Standards and reagents
11.5.2.1 Standards
11.5.2.2 Reagents
11.5.3 Apparatus <\/td>\n<\/tr>\n\n 51<\/td>\n 11.5.4 Preparation of the standard solutions
11.5.5 Sampling
11.5.6 Sample preparation
11.5.7 Procedure
11.5.8 Evaluation of results <\/td>\n<\/tr>\n\n 52<\/td>\n 11.5.9 Test report
11.6 Determination of organic solvents
11.6.1 General <\/td>\n<\/tr>\n\n 54<\/td>\n 11.6.2 Principle <\/td>\n<\/tr>\n \n 55<\/td>\n 11.6.3 Standards and reagents
11.6.3.1 Standards <\/td>\n<\/tr>\n\n 56<\/td>\n 11.6.3.2 Reagents
11.6.4 Apparatus <\/td>\n<\/tr>\n\n 57<\/td>\n 11.6.5 Preparation of the standard solutions <\/td>\n<\/tr>\n \n 58<\/td>\n 11.6.5.1 Stock solutions for the identification and determination of solvents using HS-GC-FID <\/td>\n<\/tr>\n \n 59<\/td>\n 11.6.5.2 Stock solutions for the identification and determination of solvents using GC-MS
11.6.5.3 Stock solution for the identification and determination of propane-1,2-diol
11.6.5.4 Calibration solutions <\/td>\n<\/tr>\n\n 65<\/td>\n 11.6.6 Sampling
11.6.7 Sample preparation
11.6.7.1 General
11.6.7.2 Sample preparation for identification and determination of solvents by HS-GC-FID
11.6.7.3 Sample preparation for identification of solvents by GC-MS <\/td>\n<\/tr>\n\n 66<\/td>\n 11.6.7.4 Sample preparation for determination of certain solvents by GC-MS
11.6.7.5 Sample preparation for determination of propane-1,2-diol using GC-FID
11.6.8 Procedure
11.6.8.1 Identification of solvents using HS-GC-FID <\/td>\n<\/tr>\n\n 69<\/td>\n 11.6.8.2 Identification of solvents using GC-MS <\/td>\n<\/tr>\n \n 70<\/td>\n 11.6.8.3 Determination of solvent content by HS-GC-FID <\/td>\n<\/tr>\n \n 71<\/td>\n 11.6.8.4 Determination of solvent content using GC-MS
11.6.8.5 Determination of propane-1,2-diol by GC-FID
11.6.8.6 Blank determination
11.6.9 Evaluation of results
11.6.9.1 Calculation of solvent content by HS-GC-FID <\/td>\n<\/tr>\n\n 72<\/td>\n 11.6.9.2 Calculation of solvent content by GC-MS or GC-FID
11.6.10 Test report
11.7 Combined approach for the determination of plasticisers in solvent-based adhesives and in solvent-based paints and lacquers, film-forming agents in paints and lacquers and modifiers in solvent-based paints and lacquers
11.7.1 Principle <\/td>\n<\/tr>\n\n 73<\/td>\n 11.7.2 Determination of total extract
11.7.2.1 Standards and reagents
11.7.2.2 Apparatus
11.7.2.3 Sampling
11.7.2.4 Sample preparation
11.7.2.5 Procedure <\/td>\n<\/tr>\n\n 74<\/td>\n 11.7.2.6 Evaluation of results
11.7.3 Identification of nitrocellulose
11.7.3.1 Principle
11.7.3.2 Reagents
11.7.3.3 Apparatus <\/td>\n<\/tr>\n\n 75<\/td>\n 11.7.3.4 Sampling
11.7.3.5 Sample preparation
11.7.3.6 Procedure
11.7.3.7 Evaluation of results
11.7.4 Determination of plasticisers
11.7.4.1 Principle <\/td>\n<\/tr>\n\n 76<\/td>\n 11.7.4.2 Standards and reagents
11.7.4.3 Apparatus
11.7.4.4 Preparation of the standard solution
11.7.4.5 Procedure
11.7.4.6 Evaluation of results
11.7.5 Determination of film-forming agents
11.7.5.1 Principle <\/td>\n<\/tr>\n\n 77<\/td>\n 11.7.5.2 Standards and reagents
11.7.5.3 Apparatus <\/td>\n<\/tr>\n\n 80<\/td>\n 11.7.5.4 Preparation of standard solutions <\/td>\n<\/tr>\n \n 81<\/td>\n 11.7.5.5 Sampling
11.7.5.6 Procedure
11.7.5.7 Evaluation of results <\/td>\n<\/tr>\n\n 82<\/td>\n 11.7.6 Determination of the modifiers
11.7.7 Test report <\/td>\n<\/tr>\n\n 84<\/td>\n Annex\u00a0A (normative)Environmental, health and safety precautions <\/td>\n<\/tr>\n \n 85<\/td>\n Annex\u00a0B (informative)Organic solvents <\/td>\n<\/tr>\n \n 87<\/td>\n Annex\u00a0C (informative)Maximum permitted element concentrations for the compounds permitted in ceramic and vitreous enamelling materials <\/td>\n<\/tr>\n \n 88<\/td>\n Annex\u00a0D (informative)Validation of test methods <\/td>\n<\/tr>\n \n 89<\/td>\n Annex\u00a0E (informative)Rationale
E.1 General remark
E.2 Primary packaging (4.1; 5.2; 6.2; 7.1.2; 7.2.2; 8.2.1.2.2; 8.2.2.6; 8.3.2; 8.4.3; 9.2)
E.3 Minimum age (4.1; 5.2; 6.2; 7.1.2; 7.2.3; 8.2.1.2.3; 8.2.1.3.3; 8.2.2.6; 8.3.3; 8.4.3)
E.4 Phthalates (6.1 Table 2; 8.2.2; 8.4.1) <\/td>\n<\/tr>\n\n 90<\/td>\n E.5 Benzene (6.1, Table 3; 8.2.2.4, Table 12; 8.4.1, Table 16)
E.6 Preservatives (7.2.1; 8.2.1.1; 8.3.1) <\/td>\n<\/tr>\n\n 91<\/td>\n Annex\u00a0F (informative)Significant technical changes between this European Standard and the previous version <\/td>\n<\/tr>\n \n 92<\/td>\n Annex\u00a0ZA (informative)Relationship between this European Standard and the Essential Requirements of EU\u00a0Directive 2009\/48\/EC <\/td>\n<\/tr>\n \n 93<\/td>\n Bibliography <\/td>\n<\/tr>\n<\/table>\n","protected":false},"excerpt":{"rendered":" Safety of toys – Chemical toys (sets) other than experimental sets<\/b><\/p>\n
\n\n
\n Published By<\/td>\n Publication Date<\/td>\n Number of Pages<\/td>\n<\/tr>\n \n BSI<\/b><\/a><\/td>\n 2013<\/td>\n 96<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n","protected":false},"featured_media":340776,"template":"","meta":{"rank_math_lock_modified_date":false,"ep_exclude_from_search":false},"product_cat":[1002,2641],"product_tag":[],"class_list":{"0":"post-340767","1":"product","2":"type-product","3":"status-publish","4":"has-post-thumbnail","6":"product_cat-71-040-99","7":"product_cat-bsi","9":"first","10":"instock","11":"sold-individually","12":"shipping-taxable","13":"purchasable","14":"product-type-simple"},"_links":{"self":[{"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/product\/340767","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/product"}],"about":[{"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/types\/product"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/media\/340776"}],"wp:attachment":[{"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/media?parent=340767"}],"wp:term":[{"taxonomy":"product_cat","embeddable":true,"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/product_cat?post=340767"},{"taxonomy":"product_tag","embeddable":true,"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/product_tag?post=340767"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}